Ionic compounds with delocalized anionic charge, their use...

C - Chemistry – Metallurgy – 07 – C

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C07C 381/10 (2006.01) C07C 311/48 (2006.01) C07F 7/18 (2006.01) C08K 5/36 (2006.01) G02F 1/15 (2006.01) H01M 6/16 (2006.01)

Patent

CA 2266643

The invention concerns an ionic compound of formula [R<1>X<1>(Z<1>)-Q<->-X<2>(Z<2>)-R<2>]m M<m+> in which M<m+> is a cation of valence m, each of the X<i> is S=Z<3>, S=Z<4>, P-R<3> or P-R<4>; -Q is N, CR<5>, CCN or CSO2R<5>, each of the Z<i> is =O, =NCN, =C(CN)2, =NS(=Z)2R<6> or =C[S(=Z)2R<6>]2, each of the R<i>, is Y, YO-, YS-, Y2N- or F; Y represents a monovalent organic radical or Y is a repeat unit of a polymeric fabric. The compounds are useful for preparing materials with ionic conduction or electrolyte, as catalysts and for doping polymers.

L'invention concerne un composé ionique répondant à la formule [R1X1(Z1)-Q- - X2(Z2)-R2]m M m+ dans laquelle M m+ est un cation de valence m, chacun des X i est S=Z3, S=Z4, P-R3 ou P-R4; -Q est N, CR5, CCN ou CSO2R5, chacun des Z i est =O, =NC.ident.N, =C(C.ident.N)2, =NS(=Z)2R6 ou =C[S(=Z)2R6]2, chacun des R i, est Y, YO-, YS-, Y2N- ou F, Y représente un radical organique monovalent ou bien Y est une unité de répétition d'une trame polymérique. Les composés sont utiles pour l'élaboration de matériaux à conduction ionique ou d'électrolyte, comme catalyseurs et pour le dopage de polymères.

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