Nickel catalyzed displacement reaction

Details Nickel catalyzed displacement reaction Nickel catalyzed displacement reaction

C - Chemistry, Metallurgy

07

F

260/432.8

C07F 5/06 (2006.01) C07C 1/32 (2006.01)

Patent

CA 2008133

Alkyl groups in trialkyl aluminum are displaced by .alpha.-olefins in the presence of a nickel catalyst. The displaced alkyl groups evolve as .alpha.-olefins. The displacement is fast and the catalyst is then poisoned with a catalyst poison such as lead to prevent undesired side reactions such as isomerization of .alpha.-olefins to internal olefins or dimerization to vinylidene olefins.

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