Polymerisable esters

C - Chemistry – Metallurgy – 07 – C

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260/472, 260/479

C07C 69/76 (2006.01) C08F 2/48 (2006.01) G03F 7/038 (2006.01)

Patent

CA 1080238

ABSTRACT OF THE DISCLOSURE The esters are soluble in an aqueous solution of a base be- fore exposure to actinic radiation but, on exposure to actinic radia- tion, polymerise and become insoluble in such an aqueous solution. Development of photopolymerised images does not therefore require the use of toxic or flammable organic solvents. They contain free carco- xyl groups and at least one unit of the formula I-IV Image Image I II Image Image III IV where R1 is a carbon atom chain containing specified groupings, such as one of formula -CH=CH-CO-CH=CH-, -CH=CHCO-, -COCH=CHC6H4CH= CHCO-, or Image . They are obtained by the reaction of an at least dianhydride of a polycarboxylic acid with alcoholic hydroxyl groups of an alcohol containing at least one unit of formula I-IV.

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