Preparation of lactams and related intermediates and...

C - Chemistry – Metallurgy – 07 – C

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C07C 63/26 (2006.01) C07C 45/46 (2006.01) C07C 45/62 (2006.01) C07C 49/792 (2006.01) C07C 51/27 (2006.01) C07C 51/305 (2006.01) C07D 201/10 (2006.01)

Patent

CA 1056826

ABSTRACT OF THE INVENTION Lactams alone or in combination with terephthalic acid are prepared in a sequence of steps from the carbonyl halide reaction product of a cycloparaffin and phosgene and ultimately, where desired, carbon monoxide and chlorine, by acylation of benzene or an alkyl-substituted benzene with the carbonyl chloride derivative of the cycloparaffin; and reduction and nitrosation of the resulting ketone; or, nitrosation alone, in the event the benzene nucleus is alkyl-substituted, to yield the desired lactam and aromatic acid which latter compound may be oxidized to the desired phthalic acid. I

238870

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