Process for preparing disiloxanes

C - Chemistry – Metallurgy – 07 – F

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260/445.1

C07F 7/08 (2006.01)

Patent

CA 1140143

ABSTRACT OF THE DISCLOSURE Disiloxanes of the general formula (CH2=CHR2Si)2O, where R represents a monovalent hydrocarbon radical having up to 18 carbon atoms, are obtained by reacting a compound of the formula (CH=CHRClSi)2O with a Grignard compound of the formula RMgX, where R is the same as above and X represents chlorine, bromine or iodine. These disiloxanes are thus prepared utilizing organosilicon compounds which are readily available, and substantially higher yields are produced than heretofore possible.

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