Fluorodehydroxylation of alcohols

Details Fluorodehydroxylation of alcohols Fluorodehydroxylation of alcohols

C - Chemistry, Metallurgy

07

C

260/756, 260/525

C07C 17/16 (2006.01) C07D 211/38 (2006.01) C07D 213/66 (2006.01) C07D 233/54 (2006.01) C07D 277/22 (2006.01)

Patent

CA 1063617

ABSTRACT Organic compounds containing one or more alcoholic hydroxyl groups arc transformed into fluorine compounds by reacting them with sulfur tetrafluoride in liquid hydrogen fluoride solution, at temperatures between around -80°C. and +20°C. The method can be descriptively termed "fluorodehydroxylation", because it represents the reaction: ROH ? RF.

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