Process for preparing allylic esters of carboxylic acids and...

Details Process for preparing allylic esters of carboxylic acids and... Process for preparing allylic esters of carboxylic acids and...

C - Chemistry, Metallurgy

07

C

260/627, 260/493

C07C 29/03 (2006.01) C07C 31/20 (2006.01) C07C 67/00 (2006.01) C07C 69/02 (2006.01)

Patent

CA 1048534

ABSTRACT OF THE DISCLOSURE A process for preparing allylic esters of carboxylic acids and allylic alcohols which comprises reacting in the vapor phase an olefin having an allylic carbon-hydrogen bond, a lower alkyl carboxylate ester, water and oxygen in the presence of a catalyst system comprising a Group VIII nobel metal oxidation catalyst and an acidic co-catalyst. The process is generally operable at temperatures in the range 100°C - 200°C, with alcohols being predominately formed at the higher temperatures. Preferably the olefin is propylene and the alkyl ester methyl acetate.

213945

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