Oxidation of phenyl phosphonous dihalide

C - Chemistry – Metallurgy – 07 – F

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260/537.8

C07F 9/48 (2006.01) C07F 9/42 (2006.01)

Patent

CA 1123856

OXIDATION OF PHENYL PHOSPHONOUS DIHALIDE ABSTRACT OF THE DISCLOSURE Phenyl phosphonous dihalide is oxidized according to the following reaction: Image wherein X is Cl or Br. The reaction is conducted at a temperature from about 0°C. to about 200°C. Charcoal is added to the reaction mixture when impure phenyl phosphonous dihalide is used as a starting material. The product has high purity and is stable at high temperatures. It can be used as an intermediate to prepare flame retardants, insecticides, pesticides and plasticisers. C-5363

333712

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