Removal of nitrogen oxides from industrial gases by use of...

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B01D 53/34 (2006.01)

Patent

CA 1095693

REMOVAL OF NITROGEN OXIDES FROM INDUSTRIAL GASES BY USE OF OXIDIZING SOLUTIONS IN WHICH NITRATES ARE THE OXIDANTS ABSTRACT OF THE DISCLOSURE Nitric oxide may be removed from gases which it is admixed by contacting the gases with aqueous solutions con- taining nitrate ions in sufficient concentration to oxidize the nitric oxide to nitrous acid and to retain it in the solution under stable conditions. Other oxides of nitrogen can also be absorbed producing nitrous acid which is retained in the aqueous solution in a similar manner. Thereafter, the scrubbing solution is regenerated under controlled conditions, producing a gas stream which contains the recovered nitrogen oxides in relatively high concentration,a scrubbing solution which can be recycled. The recovered nitrogen oxides may be used in the manufacture of nitric acid or other compounds or decomposed into harmless gases. The present invention relates to the removal of selected constituents from gas mixtures and, more particularly, to novel, improved methods for removing nitrogen oxides from such mixtures in order to eliminate the oxides as a source of air pollution and/or to recover the oxides for a feedstock.

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