Preparation of monomethylamine

Details Preparation of monomethylamine Preparation of monomethylamine

B - Operations, Transporting

01

J

260/609.7

B01J 29/06 (2006.01)

Patent

CA 1130817

ABSTRACT OF THE DISCLOSURE Catalytic process for producing monomethylamine from methanol and ammonia; said process comprising reacting methanol and ammonia, in such amounts so as to provide a C/N ratio, from the methanol and ammonia reactants, of 0.5-1.5, over the catalyst selected from a) mordenite wherein the primary cation is Li, Na, HNa having at least 2% Na by weight, K, Ca, Sr, Ba, Ce, Zn or Cr b) ferrierite wherein the primary metal cation is Li, Na, K, Ca, Sr, Ba, Ce or Fe c) erionite ore d) calcium erionite and e) clinoptilolite ore, at a temperature of 250-475°C and a pressure of 7-7000 kPa, a contact time, normalized to 7 kPa, of 0.1 to 60 seconds and a methanol conversion of 15-95%.

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