Polymer bound phase transfer catalyst and process for its...

C - Chemistry – Metallurgy – 07 – D

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402/353, 402/366

C07D 333/24 (2006.01) B01J 31/06 (2006.01) C08F 126/02 (2006.01) C08F 130/02 (2006.01)

Patent

CA 1126740

Abstract An improved process for converting 3-thenylbromide, by reaction with an alkali metal cyanide, to 3-thienylaceto- nitrile. New catalysts of the type termed triphase, that is a polymer bound phase transfer catalyst, are provided, said catalysts being represented as Image wherein R is a member of the group diethyl-n-butylamino, tripropylamino, tributylamino, trialkylphosphino and tri- arylphosphino; X is chlorine or bromine; and n is from 600 to 2,000,000.

333869

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