Process for preparation of aromatic hydroperoxides

C - Chemistry – Metallurgy – 07 – C

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260/642.4

C07C 409/08 (2006.01)

Patent

CA 1113506

ABSTRACT OF THE DISCLOSURE An improved process for the preparation of an aromatic hydroperoxide by oxidizing a hydroxyalkyl- substituted aromatic compound having at least one hydroxy- alkyl group directly bonded to an aromatic ring carbon of the aromatic compound and being represented by the formula Image wherein R1 and R2 each are a lower alkyl group, with hydrogen peroxide in the presence of an acid catalyst in a heterogeneous system of a water-immiscible inert aromatic hydrocarbon solvent at a reaction temperature of up to about 70°C while removing by-product water as an azeotrope with the aromatic hydrocarbon solvent in the oxidation system; characterized in that said oxidation is carried out while feeding a vapor of a water-immiscible inert aromatic hydrocarbon solvent having a temperature higher than the reaction temperature but not exceeding about 90°C into a liquid phase of the oxidation system.

337725

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