Liquid carbodiimide-uretonimine modified polymethylene...

C - Chemistry – Metallurgy – 08 – G

Patent

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400/111, 403/32

C08G 18/00 (2006.01) C08G 18/72 (2006.01) C08G 18/79 (2006.01)

Patent

CA 1333202

A process for the preparation of liquid poly- methylene polyphenylene polyisocyanate blends containing carbodiimide-uretonimine isocyanate linkages, containing a high two-ring methylene bis(phenylisocyanate) content, and light colored polyurethane foams made therefrom. The process is comprised of reacting polymethylene polyphenylene polyisocyanate with a catalytically effective amount of a carbodiimide-uretonimine promoting compound at a temperature sufficient to promote the formation of carbodiimide- uretonimine linkages and an isocyanate content of about 25 percent and the desired viscosity is reached, and then reacting that product to deactivate the carbodiimide- uretonimine catalyst, and finally blending two ring methylene bis(phenylisocyanate) with the product to produce a mixture having a two ring isocyanate content of about 60 percent of the total ring content and a viscosity comparable to standard polymeric MDI. Urethane foams made from this material are lighter in color than those formed from standard polymeric MDI.

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