Alkene coupling

Details Alkene coupling Alkene coupling

C - Chemistry, Metallurgy

07

C

260/707.3

C07C 2/24 (2006.01) B01J 23/04 (2006.01) C07C 11/02 (2006.01)

Patent

CA 2018943

A normal 1-alkene containing 3-8 carbons is coupled with itself, another such alkene, or ethane in the presence of a supported alkali metal as a catalyst and 10-100 mol %, based on the amount of alkali metal catalyst, of an alkali metal hydroxide as a co-catalyst; the support being a silica having a surface area riot greater than 5 m2/g. In preferred embodiments of the invention, the alkene is propane or a mixture of propane and ethane, the alkali metal is potassium or a potassium alloy, and the co-catalyst is potassium hydroxide.

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