Stereoselective preparation of cyclic l-amino acids

Details Stereoselective preparation of cyclic l-amino acids Stereoselective preparation of cyclic l-amino acids

C - Chemistry, Metallurgy

12

N

C12N 15/60 (2006.01) C07D 207/16 (2006.01) C12N 9/88 (2006.01) C12N 15/31 (2006.01) C12P 1/04 (2006.01) C12P 13/04 (2006.01) C12P 13/24 (2006.01) C12P 17/10 (2006.01) C12P 17/12 (2006.01) C12P 41/00 (2006.01)

Patent

CA 2449836

The invention concerns a method for producing a cyclic L-amino acid of formula (I), characterised in that it consists in reacting a L-diamino acid of formula (II) or an enantiomeric mixture comprising such a L-diamino acid and a corresponding D-diamino acid in variable proportions, in the presence of an ornithine cyclodeaminase or a polypeptide homologous to the ornithine cyclodeaminase.

L'invention concerne un procédé de production d'un L-acide aminé cyclique de formule (I), caractérisé en ce que l'on fait réagir un L-acide diaminé de formule (II), ou un mélange énantiomère comprenant un tel L-acide diaminé et un D-acide diaminé correspondant en proportions variables, en présence d'une ornithine cyclodéaminase ou d'un polypeptide homologue à l'ornithine cyclodéaminase.

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