Acrylate grouting compositions and method for grouting...

C - Chemistry – Metallurgy – 08 – L

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C08L 33/08 (2006.01) C08F 220/06 (2006.01) E03F 3/06 (2006.01) F16L 55/1645 (2006.01)

Patent

CA 1168848

-30- MAGNESIUM DIACRYLATE, POLYOL MONOACRYLATE GROUTING COMPOSITION AND METHOD FOR GROUTING JOINTS AND/OR CRACKS IN SEWER CONDUITS THEREWITH ABSTRACT OF THE DISCLOSURE This invention is concerned with an aqueous liquid composition comprising a mixture of unsaturated monomers in- cluding (1) magnesium diacrylate, (2) a polyol monoacrylate selected from hydroxyethyl acrylate and hydroxypropyl acrylate, and (3) a poly ethylenically unsaturated monomer copolymeriz- able with (1) and (2) to produce covalent cross-linking bonds in the copolymer besides the ionizable magnesium bonds. The weight ratio of (3) to the sum of (1) and (2) is in the range of about 3:97 to about 5:95. Examples of monomers that can be used as part or all of component (3) include N,N'- methylene-bis-acrylamide and ethylene glycol diacrylate. The relative proportions between the several monomers are selected to provide on polymerization a cross-linked vinyl addition polymer gel containing both covalent (non-ionic) cross-linking bonds and ionic cross-linking bonds and the relative proportions between the several components may be predetermined to render the composition suitable for applica- tion by conventional mixing packer equipment hereinafter described. In the latter equipment, means is provided to direct a second aqueous solution or suspension containing a water-soluble free radical initiator, such as a persulfate or peroxide, separately but concurrently with the first monomer-containing solution to a common distributor head of the movable packer positioned in the sewer conduit adjacent the joint or crack to be repaired, The monomer solution is provided with a tertiary amine which serves as a reducing agent, thereby providing a redox polymerization system so that when the two liquids mix, upon discharge from the head, a rapid polymerization to a polymer gel occurs at the ambient temperature.

380792

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