C-glycosidic adriamycin analogs

Details C-glycosidic adriamycin analogs C-glycosidic adriamycin analogs

C - Chemistry, Metallurgy

07

H

260/208.1

C07H 15/252 (2006.01) C07D 309/14 (2006.01) C07H 15/244 (2006.01)

Patent

CA 1330792

Abstract Disclosed herein is a new procedure for preparing the C.1-2,4-pentadienyl derivatives of 2-deoxyhexopyranoses, as well as a new procedure for allylation of daunosamine. These methods are particularly useful for the preparation of intermediates in the synthesis of adriamycin C-glycosidic analogs which are useful anti-tumor agents. These methods provide the first enabling disclosure of methods to prepare these desired adriamycin and anthrocyclinone C-glycosidic analogs.

494083

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