Catalyst complex with carbene ligand

B - Operations – Transporting – 01 – J

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B01J 31/00 (2006.01) B01J 31/16 (2006.01) B01J 31/22 (2006.01) C07C 13/00 (2006.01) C07F 9/02 (2006.01) C07F 15/00 (2006.01)

Patent

CA 2343798

Catalytic complexes including a metal atom having anionic ligands, at least one nucleophilic carbene ligand, and an alkylidene, vinylidene, or allenylidene ligand. The complexes are highly stable to air, moisture and thermal degradation. The complexes are designed to efficiently carry out a variety of olefin metathesis reactions.

L'invention se rapporte à des complexes catalyseurs comportant un atome métallique possédant des ligands anioniques, au moins un ligand carbène nucléophile, et un ligand alkylidène, vinylidène ou allénylidène. Ces complexes sont fortement stables face à l'air, l'humidité ou la dégradation thermique. Ils s'avèrent utiles pour mettre en oeuvre efficacement une variété de réactions de métathèse d'oléfines.

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