Coatings of intermediate molecular weight polyimides

C - Chemistry – Metallurgy – 09 – D

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C09D 179/08 (2006.01) C08G 73/10 (2006.01) G03F 7/038 (2006.01) H01B 3/30 (2006.01) H01B 7/29 (2006.01) H01B 7/295 (2006.01) H01L 21/312 (2006.01) H05K 1/03 (2006.01)

Patent

CA 2009085

ABSTRACT OF THE INVENTION The present invention provides a process for coating substrates with a polyimide polymer, said polymer prepared by a process of subjecting a mixture of aromatic dianhydride and aromatic diamine monomers, at least one of which contains the group (CF3 - ? - R) linking two aromatic moieties, wherein R is CF3 or phenyl, to a low temperature, substantially isothermal solution polymerization process wherein the content of the mixed monomers in solvent is maintained within the range of from about 8 to about 12% by weight solids concentration during the polymerization process. The process is conducted for a sufficient length of time and uniformity of temperature, generally below about 35°C, to achieve a weight average polyimide polymer molecular weight within the range of about 80,000 to about 135,000, more preferably of about 90,000 to about 125,000, a polyimide inherent viscosity within the range of from about 0.45 to about 0.70, and a polydispersity with the range of from about 1.7 to about 2.6. The invention also relates to articles coated with said polyimide polymer, such as silicon wafers.

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