Decomposition of organic hydroperoxides with nitrated iron...

Details Decomposition of organic hydroperoxides with nitrated iron... Decomposition of organic hydroperoxides with nitrated iron...

C - Chemistry, Metallurgy

07

C

C07C 31/02 (2006.01) C07C 29/132 (2006.01) C07C 29/50 (2006.01) C07C 33/20 (2006.01) C07C 35/08 (2006.01) C07C 37/08 (2006.01) C07C 39/04 (2006.01) C07C 45/53 (2006.01)

Patent

CA 2125459

ABSTRACT OF THE INVENTION Hydroperoxides are decomposed by contact with metalloporphyrin coordination complex catalysts in which hydrogen in the porphyrin molecule has been substituted with at least one nitro group and may be further substituted with other electron-withdrawing elements or groups, for example, halogen or halocarbons, or with hydrocarbon groups. Preferred catalysts are iron tetranitro-.beta.-octaethylporphyrins and iron tetrakispentafluorophenyl-.beta.-nitroporphyrins.

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