Dehydrogenation process for organic compounds with a...

Details Dehydrogenation process for organic compounds with a... Dehydrogenation process for organic compounds with a...

C - Chemistry, Metallurgy

07

B

C07B 35/04 (2006.01) B01J 23/62 (2006.01) B01J 27/06 (2006.01) B01J 27/13 (2006.01) B01J 35/00 (2006.01) B01J 37/18 (2006.01) B01J 37/24 (2006.01) C07C 5/32 (2006.01) C07C 5/333 (2006.01)

Patent

CA 2355484

This process for dehydrogenating the organic compound, in particular the paraffins and naphthenes is carried out in the presence of a supported catalyst comprising a group VIII metal such as platinum and tin, at least a portion of which interacts strongly with the group VIII metal in the catalyst in the reduced state. In the partially oxidized state, the catalyst contains at least 10% of tin in the form of a reduced tin species with an oxidation state 0 and the species has an isomer shift within the range of 0.80-2.60 mm/s and a quadrupolar splitting within the range of 0.65-2.00 mm/s.

On décrit un procédé pour la déshydrogénation de composés organiques, en particulier de paraffines et de naphtènes, réalisé en présence d'un catalyseur supporté renfermant un métal du groupe VIII, tel que le platine, et de l'étain dont une partie au moins est en forte interaction avec le métal du groupe VIII dans le catalyseur à l'état réduit. Le catalyseur contient à l'état partiellement oxydé au moins 10% de l'étain sous la forme d'une espèce réduite à l'état d'oxydation 0, ladite espèce présentant un déplacement isomérique IS compris entre 0,80 et 2,60 mm/s et un éclatement quadripolaire compris entre 0,65 et 2,00 mm/s.

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