Fluoroalkylated amphiphilic ligands, their metallic...

Details Fluoroalkylated amphiphilic ligands, their metallic... Fluoroalkylated amphiphilic ligands, their metallic...

C - Chemistry, Metallurgy

07

D

C07D 213/04 (2006.01) A61K 31/44 (2006.01) A61K 31/555 (2006.01) C07C 45/50 (2006.01) C07D 213/22 (2006.01) C07D 213/26 (2006.01) C07D 213/80 (2006.01) C07D 471/04 (2006.01) C07F 15/00 (2006.01)

Patent

CA 2120360

Fluoroalkylated amphiphilic ligands are derived from aromatic amines of the bipyridine (I) or phenanthroline (II) types. Transition metals, including platinum, palladium and ruthenium for complexes bearing these ligands. In formulae (I) and (II), R1 and R2 are independently a hydrogen atom, or a fluoroalkylated or hydrocarbon chain, provided at least one of R1 and R2 is a fluoroalkylated chain, and W represents a methylene, ester, ether, carbonyl or amide group. Fluoroalkylated ligands (I or II) and their complexes can be included in preparations comprising emulsions, dispersions, gels, or microemulsions, particularly in preparations for therapeutic use.

Ligands amphiphiles fluoroalkylés dérivés d'amines aromatiques de types bipyridine (I) ou phénanthroline (II). Métaux de transition, dont le platine, le palladium et le ruthénium, pour former des complexes portant ces ligands. Dans les formules (I) et (II), R1 et R2 sont, indépendamment, un atome d'hydrogène ou une chaîne hydrocarbonée ou fluoroalkylée, pourvu qu'au moins un des radicaux R1 et R2 soit une chaîne fluoroalkylée, et W est un groupe méthylène, ester, éther, carbonyle ou amide. Les ligands fluoroalkylés (I ou II) et leurs complexes peuvent être utilisés dans des préparations comprenant des émulsions, des dispersions, des gels ou des microémulsions, particulièrement dans des préparations utilisées à des fins thérapeutiques.

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