Functionalization of nanoscale articles including nanotubes...

C - Chemistry – Metallurgy – 01 – B

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Details

C01B 31/02 (2006.01) B01J 31/02 (2006.01) C01B 5/00 (2006.01) H01M 4/90 (2006.01)

Patent

CA 2680147

The present invention generally provides compositions including carbon- containing molecules, and related methods. In some cases, the present invention relates to aromatic molecules comprising functional groups bonded to the aromatic portion of the molecule, including nonplanar portions of the molecules. Methods of the invention may provide the ability to introduce a wide range of functional groups to carbon- containing molecules. In some cases, methods of the invention may be performed using relatively mild reaction conditions, such as relatively low temperature, low pressure, and/or in the absence of strong acids or strong bases. The present invention may provide a facile and modular approach to synthesizing molecules that may be useful in various applications including photovoltaic devices, sensors, and electrodes (e.g., for electrocatalysis).

L'invention se réfère de manière générale à des compositions comprenant des molécules contenant du carbone, et à des procédés associés. Dans certains cas, l'invention concerne des molécules aromatiques comprenant des groupes fonctionnels liés à la partie aromatique de la molécule, y compris des parties non planes des molécules. Les procédés de l'invention permettent d'introduire un large éventail de groupes fonctionnels dans des molécules contenant du carbone. Dans certains cas, les procédés de l'invention peuvent être mis en AEuvre dans des conditions de réaction relativement modérées, telles que des conditions de température relativement basse, de pression relativement faible et/ou sans acides forts ou bases fortes. L'invention forme une voie permettant de synthétiser facilement et de manière modulaire de molécules pouvant être utiles dans diverses applications, y compris dans des dispositifs photovoltaïques, des capteurs et des électrodes (p. ex. pour l'électrocatalyse).

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