Gas-phase polymerisation of conjugated dienes in the...

C - Chemistry – Metallurgy – 08 – F

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C08F 4/52 (2006.01) C08F 36/04 (2006.01)

Patent

CA 2217046

Conjugated dienes can be successfully gas-phase polymerised in the presence of catalysts based on rare earth allyl compounds, organic aluminium compounds and an inorganic carrier. The diene rubbers produced by this process have a high cis-1,4 double bond content and a 1,2 double bond content of over 1 %.

La polymérisation en phase gazeuse de diènes conjugués s'effectue en présence de catalyseurs à base de composés allyle des terres rares, de composés aluminium organiques et d'un support inorganique. Les caoutchoucs diéniques obtenus selon ce procédé présentent une teneur élevée en liaisons doubles cis-1,4 et une teneur en liaisons doubles 1,2 de plus de 1 %.

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