Glasses with a high refractive index and their use as...

C - Chemistry – Metallurgy – 03 – C

Patent

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Details

C03C 3/068 (2006.01) C03C 3/072 (2006.01) G02B 1/00 (2006.01) G02C 7/06 (2006.01)

Patent

CA 2248921

The invention concerns glasses characterized by the fact that they have a refractive index higher than 1.740; a dilatation coefficient .alpha., between 25 and 300 ~C, between 65 and 70 x 10-7/~C; and a Littleton point not exceeding 635 ~C but higher than 600 ~C; they have the following compositions, expressed in weight percent of oxides: SiO2 23-32.0, Al2O3 1.5-5.0, B2O3 5- 9.0, PbO 43-54.0, Li2O 0-0.5, Na2O 0-1.0, K2O 0-1.0, with Li2O + Na2O + K2O < 1.0, BaO + SrO 4-9.0, TiO2 0-4.0, ZrO2 0-2.0, La2O3 0-3.0, Nb2O5 0-3.0, As2O3 0-0.3, Sb2O3 0-0.4, with ZrO2 + La2O3 + Nb2O5 1.5-4Ø Use for the production of segments to be used in the manufacture of multifocal lenses, particularly photochromic.

Cette invention se rapporte à des verres se charactérisant par le fait qu'ils ont un indice de réfraction supérieur à 1,740; un coefficient de dilatation .alpha., à une température comprise entre 25 et 300 ·C, situé entre 65 et 70 x 10?-7¿/·C; et un point de Littleton ne dépassant pas 635 ·C mais supérieur à 600 ·C; ces verres ont la composition suivante, exprimée en pourcent en poids d'oxydes: SiO¿2?: 23 à 32,0; Al¿2?O¿3?: 1,5 à 5,0; B¿2?O¿3?: 5 à 9,0; PbO: 43 à 54,0; Li¿2?O: 0 à 0,5; Na¿2?O: 0 à 1,0; K¿2?O: 0 à 1,0; avec Li¿2?O + Na¿2?O + K¿2?O < 1,0; BaO + SrO: 4 à 9,0; TiO¿2?: 0 à 4,0; ZrO¿2?: 0 à 2,0; La¿2?O¿3?: 0 à 3,0; Nb¿2?O¿5?: 0 à 3,0; As¿2?O¿3?: 0 à 0,3; Sb¿2?O¿3?: 0 à 0,4; avec ZrO¿2? + La¿2?O¿3? + Nb¿2?O¿5?: 1,5 à 4,0. Ces verres peuvent être utilisés pour produire des segments entrant dans la fabrication de lentilles multifocales, en particulier des lentilles photochromiques.

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