Halogenated butyl rubber analogue

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 210/12 (2006.01)

Patent

CA 2113891

PROCESS FOR PRODUCING A HALOGENATED BUTYL RUBBER Abstract of the Disclosure A halogenated butyl rubber is prepared by a process wherein a monomer charge comprising isobutylene, and a conjugated diolefin having the formula Image wherein R1, R2 and R3 which may be the same or different are a methyl group or a hydrogen atom and X is bromine or chlorine together with a initiator having the formula Image wherein each R4 is an alkyl, aryl or aralkyl group, Y is preferably an alkoxy, hydroxy, peroxy ester or halide, and n is a positive whole number are introduced into a suitable reaction vessel in a specified ratio at a temperature of from about -90° to -10°C, a solution of a Lewis acid is added and the monomers are copolymerized at said temperature to form said halogenated butyl rubber, and the halogenated rubber is recovered from solution.

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