High temperature polyethylene solution polymerization process

C - Chemistry – Metallurgy – 07 – F

Patent

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C07F 7/00 (2006.01) C07C 43/23 (2006.01) C08F 2/04 (2006.01) C08F 4/659 (2006.01) C08F 4/76 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2652465

Metal complexes of polyvalent aryloxyethers appropriately substituted with sterically bulky substituents possess enhanced solubility in aliphatic and cycloaliphatic hydrocarbons and/or when employed as catalyst components for the polymerization of ethylene/ .alpha.-olefin copolymers, produce products having reduced I10/I2 values.

Aux fins de l'invention, certains complexes métalliques d'aryloxyéthers polyvalents substitués de façon appropriée avec des substituants à encombrement stérique offrent une solubilité améliorée dans des hydrocarbures aliphatiques et cycloaliphatiques et/ou en utilisation comme composants catalyseurs pour la polymérisation de copolymères d'éthylène/ .alpha.-oléfine, ce qui permet d'élaborer des produits à valeurs I10/I2 réduites.

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