Improved phlegmatization of cyclic ketone peroxides

C - Chemistry – Metallurgy – 07 – D

Patent

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Details

C07D 323/00 (2006.01) C08C 19/04 (2006.01) C08F 4/36 (2006.01) C08F 4/38 (2006.01) C08G 63/00 (2006.01) C08K 5/14 (2006.01) C08K 5/15 (2006.01) C08K 5/159 (2006.01) C09K 15/04 (2006.01)

Patent

CA 2347077

The present invention relates to a composition comprising cyclic ketone peroxide and a phlegmatizer having a 95% boil-off point falling in the range of 220-265~C, most preferably 235-250~C. A preferred peroxide is cyclic methyl ethyl ketone peroxide. Preferably, a single phlegmatizer is used. Preferred phlegmatizers are Isopar M and Soltrol 170. The invention also pertains to the use of compositions according to this invnetion in (co)polymerization and polymer modification processes.

Cette invention a trait à une composition renfermant du peroxyde de cétone cyclique et un agent de désensibilisation ayant un point d'évaporation, à 95 %, compris entre 220 et 365 ·C, de préférence, entre 235 et 250 ·C. Le peroxyde préféré, dans le cadre de cette invention, est un peroxyde de cétone de méthyl-éthyle. On utilise, de préférence, un seul agent de désensibilisation. Les agents de désensibilisation préférés sont l'Isopar? M et le Soltrol? 170. L'invention concerne également l'emploi qui est fait de ces compositions dans des processus de (co)polymérisation et de modification de polymères.

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