Isoalkane-olefin alkylation process

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 9/16 (2006.01) B01J 31/06 (2006.01) B01J 31/10 (2006.01) C07C 2/58 (2006.01) C07C 2/62 (2006.01)

Patent

CA 2080539

ABSTRACT OF THE DISCLOSURE A process for the alkylation of isoalkanes with olefins using sulfonated polymer catalysts, where the catalyst has a moisture content of less than about 1.0%, is disclosed. Preferred catalysts include sulfonated macroporous crosslinked vinylaromatic polymers and sulfonated carbonaceous adsorbent polymers having surface areas greater than about 400 square meters per gram. The process is useful for the synthesis of branched alkanes which may be used in high- octane gasolines, e.g., trimethylpentanes from isobutane and butenes.

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