Isomerization of epoxyalkenes to 2,5-dihydrofurans and...

C - Chemistry – Metallurgy – 07 – D

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C07D 307/28 (2006.01) B01J 31/02 (2006.01) B01J 31/12 (2006.01) C07D 493/08 (2006.01)

Patent

CA 2077660

Disclosed are processes for the isomerization of epoxyalkenes to dihydrofurans by contacting an epoxyalkene with a catalyst comprising a quaternary organic onium iodide compounds, optionally deposited on a non-acidic support and/or in combination with a Lewis acid co-catalyst. The catalyst may comprise a supported catalyst, an unsupported catalyst or a solution of the catalyticalty-active components in an inert, organic solvent.

Procédés d'isomérisation d'époxyalcènes en dihydrofurannes, selon lesquels l'époxyalcène est contacté par un catalyseur comprenant un composé organique quaternaire de iodure d'onium déposé facultativement sur un support non acidifère et/ou utilisé en combinaison avec un co-catalyseur à l'acide de Lewis. Le catalyseur peut comporter un catalyseur supporté, un catalyseur non supporté ou une solution de composants catalytiquement actifs dans un solvant organique inerte.

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