Layer elements and their production

B - Operations – Transporting – 05 – D

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B05D 1/20 (2006.01) B01J 31/16 (2006.01) B01J 31/18 (2006.01) C09D 183/08 (2006.01) D06M 13/50 (2006.01) G03G 5/06 (2006.01)

Patent

CA 1328786

- 27 - Abstract of the Disclosure: A layer element comprises a base having a hydrophobic surface and, applied on this, one or more solid, thin, ordered layers of defined uni- form and regular structure, in particular monolayers or multilayers, having a uniform orientation of the layer- forming molecules in one direction. The said layers are formed from a metallomacrocyclic polymer which is fusible and/or soluble in an organic, water-immiscible solvent and is of the general formula [M(Pcyc)O]n, where M is Si, Ge or Sn, (Pcyc) is a complex-forming centrosymmetric poly- cyclic ring system, in particular a phthalocyanine ring system having hydrophobic substituents, and n is the mean degree of polymerization and is equal to or greater than 3. The novel layer elements can advantageously be pro- duced by the Langmuir-Blodgett technique, in which a solid- like monolayer Produced on a water surface from the metallo- macrocyclic polymers is transferred to a substrate having a hydrophobic surface by immersion and withdrawal of the said substrate. The layer elements according to the in- vention can be used, for example, as optical filters, eg. grey filters, interference filters or polarization fil- ters, in electrochemistry and the electrical industry, for example as electrodes, sensors, catalysts etc., as photosensitive elements for electrophotography, and for many other applications.

536869

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