Lead-and cadmium-free glass composition for glazing,...

C - Chemistry – Metallurgy – 03 – C

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C03C 8/14 (2006.01) C03C 3/091 (2006.01) C03C 8/02 (2006.01) C03C 8/06 (2006.01)

Patent

CA 2279785

The invention relates to lead-free and cadmium-free glass for glazing, enamelling and decorating glasses or glass-ceramics which have a low coefficient of thermal expansion of less than 2 x 10-6/K, having the composition (in % by weight) 0-6 Li2O, 0-5 Na2O, 0 to less than 2 K2O, where the sum Li2O + K2 + Na2O is between 2 and 12, 0-4 MgO, 0-4 CaO, 0-4 SrO, 0-1 BaO, 0-4 ZnO, 3 to less than 10 Al2O3, 13-23 B2O3, 50-65 SiO2, 0-4 TiO2, 0-4 ZrO2 and 0-4 F, as replacement for oxygen and containing up to 30% by weight of a pigment which is resistant at the firing temperature, where the glass is suitable for glazing, enamelling and decoration in both primary and secondary firing, and both the full-area and sparse glaze, enamel or decoration layers have low abrasion susceptibility after firing, and it relates to processes for the production of a glass-ceramic coated therewith.

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