Metal complexes of bis-indole compounds and aqueous...

C - Chemistry – Metallurgy – 07 – D

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C07D 519/04 (2006.01) A61K 31/475 (2006.01) A61K 47/26 (2006.01)

Patent

CA 1272192

23305-1029(S) ABSTRACT The invention relates to new aqueous pharmaceutical compositions containing as active ingredient a pharmaceutically acceptable complex of a bis-indole compound with a bi- or multi- valent metal ion in a therapeutically effective amount. The in- vention further relates to complexes formed between a bis-indole compound and a bi- or multivalent metal ion of the formula (I): Image (1) According to another aspect of the invention there is provided a process for the preparation of a pharmaceutically acceptable metal complex of a bis-indole compound and optionally stable aqueous pharmaceutical compositions containing said metal complex, in which a solution of a bis-indole compound or a phar- maceutically acceptable salt thereof in an aqueous medium is reacted with a non-toxic water soluble salt of a bi- or multi- valent metal capable of complexation, at a pH of 3.0 to 6.0, optionally in the presence of or followed by the addition of a conventional pharmaceutical carrier and/or further additive, or, 23305-1029(S) if desired, the obtained complex is isolated. The aqueous pharmaceutical compositions according to the invention have substantially increased stability.

492974

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