Method for producing tin-free steel strips having improved...

C - Chemistry – Metallurgy – 25 – D

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204/25.5

C25D 5/18 (2006.01) C25D 11/38 (2006.01)

Patent

CA 1238293

ABSTRACT OF THE DISCLOSURE Tin-free steel sheets are produced by chromium plating a thin steel sheet through cathodic electrolysis in a chromium-containing bath to deposit a metallic chromium layer, reversely electrolyzing the chromium plated steel steet by a successive anodizing treatment in the same or another chromium-containing bath, and subjecting the reversely electrolyzed steel sheet to an electrolytic chromate treatment in an aqueous chromate solution. The adhesion of lacquer to the TFS sheet is improved by carrying out the electrolytic chromate treatment in a chromate solution which contains chromic acid, chromates or dichromates as a main ingredient and sulfuric acid, sulfates, thiocyanates, sulfonic acids or sulfonates as an assistant ingredient, in a molar ratio of H2SO4/CrO3 between 1/1000 and 1/100 provided that the main and assistant ingredients are converted into CrO3 and H2SO4, respectively.

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