Method of duplicating plastics information carriers, as well...

C - Chemistry – Metallurgy – 08 – F

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402/122, 402/182

C08F 20/20 (2006.01) G03F 7/00 (2006.01) G11B 3/70 (2006.01) G11B 23/00 (2006.01)

Patent

CA 1111194

ABSTRACT: The invention relates to a method of repro- ducing plastics record carriers, in particular dupli- cating video records. According to the invention, a metal die is used which is provided with a thin-liquid moulding resin of a particular composition which can be polymerized by radiation. A radiation-pervious substrate which is manufactured from synthetic ma- terial, for example polymethylmethacrylate, is pro- vided on the moulding resin. The moulding resin is exposed to light via the substrate after which the cured moulding resin together with the substrate con- nected thereto is removed from the die. The moulding resin used in the process comprises low-molecular monomers or oligomers which contain on an average 25-70% by weight of hydrocarbon groups and/or phenyl groups. The moulding resin is aprotic and has a functionality as regards unsaturatedness which is between the values 2 and 6. A suitable moulding resin contains mono-, tri- or tetra esters of acylic acid. The moulding resin preferably has a swelling capacity with respect to the substrate and for that purpose preferably comprises a vinylmonomer. The metal die used in the method preferably is a quite flat die which is obtained by providing the mastor disk which is a flat glass plate with information track with a nickel layer, gluing hereon a flat stiffening plate and then removing the master disk. The resulting father disk may be used as a die. Alternatively, further metal copies may be made here from which are provided in a simpler manner with a flat stiffening plate. The invention also extends to the moulding resin, substrate and die used in the method, as well as to the resulting plastics record carriers.

288224

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