Method of producing a glass article having a graded...

C - Chemistry – Metallurgy – 03 – C

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C03C 23/00 (2006.01) C02F 5/14 (2006.01) C03B 37/016 (2006.01)

Patent

CA 1119808

METHOD OF PRODUCING A GLASS ARTICLE HAVING A GRADED REFRACTIVE INDEX PROFILE OF A PARABOLIC NATURE ABSTRACT OF THE DISCLOSURE: A method of producing a glass article having a graded refractive index profile of a parabolic nature is disclosed. The method comprises soaking a preform having a porous matrix with interconnected pores into a stuffing solution containing at least one index modifying dopant of predetermined solubility in the stuffing solution for a time interval to fill the pores with the dopant solution, precipitating the dopant into the porous matrix approximately uniformly throughout, soaking the preform into a solvent solution having a solubility for the dopant lower than the solubility of the dopant in the stuffing solution for a time interval sufficient to cause substantially all of the dopant to redissolve and for diffusion to take place out of the porous matrix in such a way that the dopant concentration decreases as a function of radial distance from the central axis, precipitating the dopant in the porous matrix by reducing the temperature of the preform to a level such that the dopant is precipitated out of solution, removing the solvent and where necessary decomposi- tion products from the preform, and heating to consolidate the preform to produce a glass article having a graded refractive index profile of the parabolic nature.

342760

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