C - Chemistry – Metallurgy – 08 – L
Patent
C - Chemistry, Metallurgy
08
L
31/79, 18/798, 4
C08L 23/00 (2006.01) B29C 47/00 (2006.01) C08K 5/134 (2006.01) C08K 5/3492 (2006.01) C08L 23/04 (2006.01) C08L 23/10 (2006.01) C09K 15/16 (2006.01) C09K 15/20 (2006.01)
Patent
CA 2034744
MULTI-COMPONENT STABILIZER SYSTEM FOR POLYOLEFINES PIGMENTED WITH PHTHALOCYANINE PIGMENTS ABSTRACT OF THE DISCLOSURE Excellent color stabilization as well as fiber integ- rity is obtained in bright sunlight and at relatively high temperature, in polyolefine (Po) articles pigmented with phthalocyanine pigments, by combining the pigment with two `large molecule' primary stabilizers, the first a hindered amine light stabilizer (HALS) and the second a 3,5-disub- stituted-tert-butyl-4-hydroxybenzoate (3,5-DHBZ). The first contains at least one triazine ring, and each substitutable position on each triazine ring is substituted with an oxo- piperazinyl group; the second is a hindered phenol with an ester group in the para- position. Stabilization of the PO's color is obtained for as long as the PO articles themselves are stabilized by the combination of primary stabilizers. With the combination, phthalocyanine pigmented articles are not only thermooxidatively and light-stabiliz- ed, but there is exceptionally low color fade. Because fibers are extruded twice for better distribution of pig- ment, a small amount, no more than 0.1 phr of secondary melt-stabilizers, may be used. Blue- and green-pigmented PO articles in particular, so stabilized, exhibit less than a +2 change in color (color fading) due to degradation of the pigment, over exposure resulting in absorption of 1240 kjoules. Such exposure, deemed equivalent to exposure to sunlight for about 2 years in Florida at a 45° South expo- sure, of PP fibers pigmented with the combination of pri- mary stabilizers suffer essentially no loss of color due to degradation of the pigment.
Kletecka George
Lai John T.
Son Pyong N.
Kletecka George
Lai John T.
Son Pyong N.
Swabey Ogilvy Renault
The B. F. Goodrich Company
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