Nanocomposites formed by onium ion-intercalated clay and...

C - Chemistry – Metallurgy – 08 – L

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C08L 63/00 (2006.01) C08K 3/34 (2006.01) C08K 9/04 (2006.01)

Patent

CA 2299705

Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant onium ion spacing agent and an anhydride- curable epoxy resin. The intercalant onium ion spacing agent converts the interlayer region of the layered materials from hydrophilic to hydrophobic, therefore, the anhydride-curable epoxy resin can be easily intercalated into the interlayer spacing. The co-presence of the co-intercalant anhydride-curable epoxy resin in the interlayer space provides surprising increase in glass transition temperature for anhydride-curable epoxy resin matrix polymer/co- intercalant compounded nanocomposites. The nanocomposites (e.g., epoxy-clay) prepared from the intercalants demonstrate enhanced mechanical, thermal and chemical resistance compared with pristine polymer matrices.

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