O2-arylated or o2-glycosylated 1-substituted...

C - Chemistry – Metallurgy – 07 – D

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C07D 295/22 (2006.01) C07C 291/08 (2006.01) C07D 207/16 (2006.01) C07D 213/64 (2006.01) C07D 239/34 (2006.01) C07D 295/28 (2006.01) C07H 15/00 (2006.01)

Patent

CA 2266908

Diazeniumdiolates, wherein the N1 position is substituted by an inorganic or organic moiety and the O2-oxygen is bound to a substituted or unsubstituted aromatic group, are provided. Also provided are O2-glycosylated 1-substituted diazen-1-ium-1,2-diolates (O2-glycosylated diazeniumdiolates) and O2- substituted 1-[(2-carboxylato)pyrrolidin-1-yl]diazen-1-ium-1,2-diolates (1-[(2- carboxylato)pyrrolidin-1-yl]diazeniumdiolates). The O2-aryl diazeniumdiolates are stable with respect to the hydrolytic generation of nitric oxide in neutral to acidic solutions and generate nitric oxide in basic or nucleophilic environments or microenvironments. Also provided are compositions, including pharmaceutical compositions, comprising such compounds and methods of using such compounds.

Cette invention se rapporte à des diazéniumdiolates, dans lesquels la position N?1¿ est substituée par une fraction inorganique ou organique et l'oxygène O?2¿ est lié à un groupe aromatique substitué ou insubstitué. Cette invention présente également des diazén-1-ium-1,2-diolates 1-substitutés O?2¿-glycosylés (diazéniumdiolates O?2¿-glycosylés) et des 1-[(2-carboxylato)pyrrolidin-1-yl]diazén-1-ium-1,2-diolates O?2¿-substitués (1-[(2-carboxylato)pyrrolidin-1-yl]diazéniumdiolates). Les diazéniumdiolates O?2¿-aryle sont stables par rapport à la production hydrolytique d'oxyde nitrique dans des solutions neutres à acides et génèrent de l'oxyde nitrique dans des environnements ou des microenvironnements basiques ou nucléophiles. Cette invention se rapporte également à des compositions, y compris des compositions pharmaceutiques, comprenant ces composés, ainsi qu'à des procédés d'utilisation de ces composés.

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