Oxidation catalyst and process for its preparation and...

B - Operations – Transporting – 01 – J

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B01J 21/18 (2006.01) B01J 23/74 (2006.01) B01J 23/89 (2006.01) B01J 31/18 (2006.01) B01J 35/02 (2006.01) B01J 37/02 (2006.01) C07C 209/68 (2006.01) C07C 227/00 (2006.01) C07F 9/38 (2006.01) B01J 23/62 (2006.01) B01J 35/00 (2006.01) B01J 35/10 (2006.01) B01J 37/08 (2006.01)

Patent

CA 2476255

An oxidation catalyst is prepared by pyrolyzing a source of iron and a source of nitrogen on a carbon support. Preferably, a noble metal is deposited over the modified support which comprises iron and nitrogen bound to the carbon support. The catalyst is effective for oxidation reactions such as the oxidative cleavage of tertiary amines to produce secondary amines, especially the oxidation of N-(phosphonomethyl)iminodiacetic acid to N-(phosphonomethyl)- glycine.

Un catalyseur d'oxydation est préparé par pyrolyse d'une source de fer et d'une source d'azote sur un support de carbone. De préférence, un métal noble est déposé sur le support modifié lequel comprend du fer et de l'azote liés au support de carbone. Le catalyseur est efficace pour des réactions d'oxydation telles que le clivage oxydatif d'amines tertiaires pour produire des amines secondaires, notamment l'oxydation d'acide N-(phosphonométhyl)iminodiacétique en N-(phosphonométhyl)-glycine.

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