Palladium catalyzed oxy-acetylation of phenyl acetate to...

C - Chemistry – Metallurgy – 07 – C

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260/489, 260/579

C07C 49/825 (2006.01) C07C 67/00 (2006.01) C07C 67/29 (2006.01) C07C 69/14 (2006.01)

Patent

CA 1167057

ABSTRACT Phenyl acetate is converted to predominantly acetoxyacetophenones by a palladium catalyst in the presence of an oxy-acetylation amount of oxygen, acetic anhydride, acetic acid at elevated temperatures and pressures. Use of optional group lA metal acetate or a mineral acid also affects products and isomers distribution.

373935

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