Ph electrode glass compositions

C - Chemistry – Metallurgy – 03 – C

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261/13, 324/28.2

C03C 3/04 (2006.01) C03C 3/095 (2006.01) C03C 4/18 (2006.01) G01N 27/36 (2006.01)

Patent

CA 1156680

ABSTRACT OF THE DISCLOSURE A glass composition for use in pH-responsive glass electrodes, and a glass electrode having a pH-responsive membrane of such glass, which composition consists essen- tially of (in mole percent on the oxide basis): a. from about 30 to about 37 mole percent Li2O; b. from 0 to about 4 mole percent of at least one oxide selected from the group consisting of Cs2O and Rb2O; c. from about 2 to about 12 mole percent of at least one oxide selected from the group consisting of La2O3 and Pr2O3; d. from about 2 to atout 10 mole percent of at least one oxide selected from the group consisting of Ta2O5 and Nb2O5; e. from 0 to about 4 mole percent UO2; and f. the balance SiO2: with the proviso that there is present in the composition at least about 2 mole percent of at least one oxide selected from the group consisting of Pr2O3 and Nb2O5.

376207

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