C - Chemistry – Metallurgy – 09 – K
Patent
C - Chemistry, Metallurgy
09
K
C09K 11/08 (2006.01) C07F 15/00 (2006.01) H01L 51/00 (2006.01) H01L 51/30 (2006.01)
Patent
CA 2448718
Red-emitting complexes [Os(pypz)2L2], L = PPh2Me (1) and L = PPhMe2 (2), or [Os(pytz)2L2], L = PPh2Me (3), were isolated from treatment of blue- emitting complex [Os(pypz)2(CO)2] or its relevant analogue [Os(pytz)2(CO)]2 with Me3NO to eliminate the coordinated CO ligands, followed by addition of the phosphine ligands. Highly intensive phosphorescent emission was observed for complexes 1 - 3 in CH2Cl2 solution maximized at 617, 632 and 649 nm, respectively. A preliminary investigation of the electroluminescent properties of these compounds on OLEDs was conducted using these Os(II) materials in emitting layers, exhibiting the best performances ever reported for the Os(II) based electroluminescent materials.
Carty Arthur
Chi Yun
Tao Ye
Tung Yung-Liang
Carty Arthur
Chi Yun
Mckay Margaret H.
National Research Council Of Canada
Tao Ye
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