Polymer-modified electrode for energy storage devices and...

H - Electricity – 01 – G

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H01G 9/042 (2006.01) H01G 9/00 (2006.01) H01M 4/60 (2006.01)

Patent

CA 2474484

An energy storage device (1), such as a battery or supercapacitor, that includes at least two electrodes (2 & 3), at least one of the electrodes (2) includes an electrically conducting substrate having a layer of energy accumulating redox polymer complex compound of transition metal having at least two different degrees of oxidation, which polymer complex compound is formed of stacked transition metal complex monomers. The stacked transition metal complex monomers have a planar structure with the deviation from the plane of no greater than 0.1 nm and a branched system of conjugated .pi.- bonds. The polymer complex compound of transition metal can be formed as a polymer metal complex with substituted tetra-dentate Schiff's base. The layer thickness of redox polymer is within the range 1 nm-20 ~m.

L'invention concerne un dispositif de stockage d'énergie, p. ex. accumulateur ou supercondensateur, qui comprend au moins deux électrodes. Au moins une de celles-ci comporte un substrat électriquement conducteur présentant une couche de complexe de coordination polymère redox d'accumulation d'énergie, constituée d'un métal de transition qui présente au moins deux degrés d'oxydation ; ledit complexe de coordination polymère est formé de monomères de coordination de métal de transition empilés. Ces monomères empilés ont une structure plane, présentent une déviation par rapport au plan ne dépassant pas 0,1 nm et un système ramifié de liaisons .pi. conjuguées. Le complexe de coordination polymère de métal de transition peut être formé comme complexe métallique polymère avec une base de Schiff tétradentée substituée. L'épaisseur de la couche polymère redox est comprise entre 1 nm et 20 µm.

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