Polyurethanes cured with...

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 271/08 (2006.01) C08G 18/10 (2006.01) C08G 18/72 (2006.01) C08G 18/76 (2006.01)

Patent

CA 2150386

Polyurethane prepolymers are disclosed prepared with mononuclear aromatic diisocyanate such as toluene diisocyanate and an aliphatic diisocyanate such as H12MDI. These prepolymers can be cured with 4,4'- methylene-bis-(3-chloro-2,6-diethylaniline) to form a cured urethane elastomer with reduced propensity to crack during the curing process, extended pour life (a slower rate of viscosity buildup after curative and prepolymer are mixed), low hysteresis, and a low level of free toluene diisocyanates and/or other toxic or volatile substances to increase worker safety during processing. It has also been found that prepolymers made from toluene diisocyanate and cured with a blend of two aromatic diamine curatives yield urethane elastomers with the same reduced propensity to crack during the curing process.

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