Preparation of alternating olefin/carbon monoxide copolymers...

C - Chemistry – Metallurgy – 08 – G

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C08G 67/02 (2006.01) B01J 31/18 (2006.01) B01J 31/24 (2006.01)

Patent

CA 2091028

A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by: (a) Pd(O2CNEt2)2(NHET2)2 supported on a solid carrier preferably constituted by hydroxylated silica, (b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorus atoms capable of Linking to Pd atom by dative bonds, (c) a mineral or organic acid. Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).

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