Process and device for selective hydrogenation by catalytic...

C - Chemistry – Metallurgy – 07 – C

Patent

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23/399, 260/709,

C07C 11/02 (2006.01) B01D 3/00 (2006.01) B01J 8/02 (2006.01) C07C 5/27 (2006.01) C07C 7/08 (2006.01) C10G 45/00 (2006.01) C10G 45/40 (2006.01) C10G 45/44 (2006.01) C10G 49/00 (2006.01)

Patent

CA 2194076

he invention concerns a reactive distillation device comprising a distillation zone, associated with a reaction zone which is at least partly inside the distillation zone and includes at least one catalytic bed, in which the charge is converted in the presence of a catalyst and at least one gas stream including hydrogen. Any catalytic bed in the internal part of the said reaction zone is traversed by an ascending cocurrent flow of said gas stream and the liquid. The invention also concerns processes for the selective hydrogenation of light unsaturated hydrocarbons, mainly olefins and benzene, contained in a mixture made up primarily of hydrocarbons with at least five carbon atoms per molecule, and processes for the hydroisomerization of at least part of the butene-1 contained in a charge consisting mainly of olefin hydrocarbons, including isobutene, and butene-1 and butene-2 in a ratio that basically corresponds to thermodynamic equilibrium.

L'invention concerne un dispositif de distillation réactive comportant une zone de distillation, associée à une zone réactionnelle au moins en partie interne à ladite zone de distillation et comprenant au moins un lit catalytique, dans laquelle onréalise la transformation de la charge, en présence d'un catalyseur et d'au moins un flux gazeux comprenant de l'hydrogène, caractérisé en ce que tout lit catalytique de la partie interne de ladite zone réactionnelle est traversé à co-courant ascendant par ledit flux gazeux et le liquide. L'invention concerne aussi des procédés d'hydrogénation sélective des hydrocarbures insaturés légers, principalement des oléfines éventuelles et du benzène, compris dans un mélange constitué en majeure partie d'hydrocarbures comportant au moins cinq atomes de carbone par molécule, ainsi que d'hydroisomérisation d'au moins une partie du butène-1 compris dans une charge comprenant en majeure partie des hydrocarbures oléfiniques dont de l'isobutène, ainsi que du butène-1 et des butènes-2 en rapport correspondant sensiblement à l'équilibre thermodynamique.

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