Process for conjointly preparing methyl tert-butyl ether and...

C - Chemistry – Metallurgy – 07 – C

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260/648, 260/639

C07C 11/09 (2006.01) C07C 7/148 (2006.01) C07C 41/06 (2006.01) C07C 43/04 (2006.01)

Patent

CA 1151217

Abstract of the Disclosure: A process for conjointly pre- paring methyl tert.-butyl ether and obtaining isobutene from an isobutene-containing C4-hydrocarbon mixture, wherein a) the C4-hydrocarbon mixture is reacted, in one or more etherification stages, with methanol and a pri- mary C3 or C4-alcohol in the presence of an acid con- densing agent, b) the resulting reaction mixture or mixtures are then separated into a fraction containing the unconverted hydro- carbons, the methyl tert.-butyl ether and a fraction containing the C3- or C4-alkyl tert.- butyl ether and c) thereafter the C3- or C4-alkyl tert.-butyl ether is decomposed at r.. elevated temperature, in the presence of an acid catalyst, into isobutene and primary C3- or C4-alcohol.

355097

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