Process for the preparation of acyloxybenzenesulfonic acids...

C - Chemistry – Metallurgy – 07 – C

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260/489, 260/481

C07C 303/06 (2006.01) C11C 3/00 (2006.01)

Patent

CA 1281738

Abstract of the disclosure A process for the preparation of acyloxybenzenesulfonic acids and salts thereof, of the formula Image in which R is C1-C17-alkyl or C2-C17-alkenyl and M is an alkali or alkaline earth metal, ammonium or hydrogen, including the stages of (a) sulfonation of phenol, if appropriate (b) thermal treatment of the sul- fonated phenol, (c) esterification of the sulfonated phenol and if appropriate (d) neutralization of the ester, wherein the sulfonation of the phenol is carried out with sulfuric acid or oleum and the water of reaction is re- moved during or after stage (b) by distillation and/or by reaction with a dehydrating agent.

521292

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