Processes for producing adipic acid from fermentation broths...

C - Chemistry – Metallurgy – 07 – C

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Details

C07C 51/43 (2006.01) C07C 51/02 (2006.01) C12P 7/44 (2006.01) C12P 13/00 (2006.01) C07C 55/14 (2006.01)

Patent

CA 2738164

Processes for making AA from either a clarified DAA-containing fermentation broth or a clarified MAA-containing fermentation broth that include distilling the broth under super atmospheric pressure at a temperature of > 100°C to about 300°C to form an overhead that comprises water and ammonia, and a liquid bottoms that includes AA, and at least about 20 wt% water; cooling the bottoms to a temperature sufficient to cause the bottoms to separate into a liquid portion and a solid portion that is substantially pure AA; and separating the solid portion from the liquid portion. A method also reduces the broth distillation temperature and pressure by adding an ammonia separating and/or water azeotroping solvent to the broth.

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